Glacial Acetic Acid CAS 64-19-7
Glacial Acetic Acid CAS 64-19-7
  • Chemical Name:Acetic Acid 64-19-7
    CAS No.: 64-19-7
    Product Categories:Chemical Reagents
    Molecular Formula:C2H4O2
    Formula Weight:60.05
    Appearance:Transparent liquid

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Base

Acetic acid, commonly known as vinegar acid (AcOH), is named after its primary component in vinegar and is one of the most important fatty acids. In nature, it typically exists in free form or as an ester in many plants.

Its molecular formula is CH₃COOH. Pure acetic acid is a colorless liquid with a pungent odor. It has a melting point of 16.6°C, a boiling point of 117.9°C, and a relative density of 1.049 (20/4°C). It is soluble in water, ethanol, glycerol, ether, and carbon tetrachloride; it is insoluble in carbon disulfide. Anhydrous acetic acid solidifies into an ice-like substance at low temperatures, commonly known as glacial acetic acid.

It is corrosive. As a weak organic acid, it exhibits the general properties of acids and can undergo esterification reactions with alcohols.

Properties
Melting point 16.2°C(lit.)
Boiling point 117-118 °C(lit.)
density 1.049 g/mL at 25 °C(lit.)
vapor density 2.07 (vs air)
vapor pressure 11.4 mm Hg ( 20 °C)
refractive index n20/D1.371(lit.)
FEMA 2006 | ACETIC ACID
Fp 104°F
storage temp. Store below +30°C.
solubility alcohol: miscible(lit.)
form Solution
pka 4.74(at 25℃)
Specific Gravity 1.0492 (20℃)
color colorless
PH 3.91(1 mM solution);3.39(10 mM solution);2.88(100 mM solution);
Odor Strong, pungent, vinegar-like odor detectable at 0.2 to 1.0 ppm
PH Range 2.4 (1.0M solution)
Odor Threshold 0.006ppm
Odor Type acidic
explosive limit 4-19.9%(V)
Water Solubility miscible
λmax λ: 260 nm Amax: 0.05 λ: 270 nm Amax: 0.02 λ: 300 nm Amax: 0.01 λ: 500 nm Amax: 0.01
JECFA Number 81
Merck 14,55
BRN 506007
Henry’s Law Constant 133, 122, 6.88, and 1.27 at pH values of 2.13, 3.52, 5.68, and 7.14, respectively (25 °C, Hakuta et al., 1977)
Exposure limits TLV-TWA 10 ppm ~25 mg/m3) (ACGIH, OSHA, and MSHA); TLV-STEL 15 ppm (37.5 mg/m3) (ACGIH).
Dielectric constant 4.1(2℃)
Stability: Volatile
LogP -0.170
CAS DataBase Reference 64-19-7(CAS DataBase Reference)
NIST Chemistry Reference Acetic acid(64-19-7)
EPA Substance Registry System Acetic acid (64-19-7)

 

Certificate of Analysis
Commodity Acetic acid Standard GB/T 1628-2008
Production batch number 234IPA2510215 Inspection date 20251025
Product date 20251025 Expiry date 20261024
Items Unit Index Result
Superior First-grade Qualified
Chromaticity(in Hazen)(Pt-Co)≤ 10 20 30 5
Acetic acid content≥ % 99.8 99.5 98.5 99.9
Moisture content ≤ % 0.15 0.20 _ 0.07
Formic acid content≤ % 0.05 0.10 0.30 0.003
Acetaldehyde content ≤ % 0.03 0.05 0.10 0.01
Evaporation residue≤ % 0.01 0.02 0.03 0.003
Fe≤ % 0.00004 0.0002 0.0004 0.00002
Permanganate – reducing substances≥ min 30 5 _ 〉30
Appearance Transparent liquid without suspended solids and mechanical impurities Superior
Applications

Acetic acid is a fundamental organic acid and a key raw material in the chemical industry. It is mainly used in the production of acetic anhydride, vinyl acetate, acetate esters, metal acetates, chloroacetic acid, and cellulose acetate.

It serves as an important intermediate in pharmaceuticals, dyes, pesticides, and various organic syntheses. Acetic acid also functions as a solvent, analytical reagent, and non-aqueous titration solvent, and is widely used in oxidation reactions.

In the food industry, it acts as an acidulant, flavor enhancer, and preservative—used in seasonings, vinegar, canned foods, cheeses, and aromatic wines (0.1–0.3 g/kg).

Additionally, acetic acid and its salts (e.g., sodium, potassium, and aluminum acetates) are used as buffers, catalysts, and auxiliaries in textile dyeing, leather tanning, and biochemical applications.

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Q5:How should spills or leaks be handled?
A: Immediately evacuate non-essential personnel, eliminate all ignition sources, and proceed with cleanup only after ensuring personal protection (wearing appropriate PPE). Small spills can be absorbed with inert materials (like sand or earth), collected in a sealed container, and disposed of according to local regulations. Prevent material from entering sewers or drains.