Dichloromethane CAS 75-09-2
Dichloromethane CAS 75-09-2
  • Chemical Name:Dichloromethane
    CAS No.:75-09-2
    Product Categories:Organic Chemistry
    Molecular Formula:CH2Cl2
    Formula Weight:84.93
    Appearance:Colorless, transparent liquid

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Base

Dichloromethane is a compound formed by replacing two hydrogen atoms in a methane molecule with chlorine atoms, with the molecular formula CH₂Cl₂. It is a colorless, transparent, heavier-than-water, volatile liquid with an ether-like odor and a sweet taste.

It is non-flammable but forms an explosive mixture when mixed with high concentrations of oxygen. Dichloromethane is slightly soluble in water and miscible with most common organic solvents. It is also miscible with other chlorinated solvents, ether, ethanol, and N,N-dimethylformamide in any proportion. At room temperature, dichloromethane is poorly soluble in liquid ammonia but dissolves rapidly in phenols, aldehydes, ketones, glacial acetic acid, triethyl phosphate, formamide, cyclohexamine, and ethyl acetate. Relative density: 1.3266 (20/4°C).

Melting point: -95.1°C. Boiling point: 40°C. A non-flammable low-boiling-point solvent, it is commonly used as a substitute for flammable petroleum ether, ether, etc., and can also be used as a dental local anesthetic, refrigerant, and fire extinguishing agent, etc.

Autoignition temperature: 640°C. Viscosity (20°C): 0.43 mPa·s. Refractive index nD (20°C): 1.4244. Critical temperature: 237°C. Critical pressure: 6.0795 MPa. Upon thermal decomposition, it produces HCl and trace amounts of phosgene. When heated with water over an extended period, it forms formaldehyde and HCl. Further chlorination yields CHCl₃ and CCl₄.
Properties
Pure dichloromethane has no flash point. A solvent mixture containing equal volumes of dichloromethane and gasoline, solvent naphtha, or toluene is non-flammable.

However, when dichloromethane is mixed with acetone or methanol in a 10:1 ratio, the mixture has a flash point, and its vapor forms an explosive mixture with air, with an explosive limit of 6.2% to 15.0% (by volume).

Properties
Melting point -97°C
Boiling point 39.8-40°C mm Hg(lit.)
Density 1.325 g/mL at 25 °C(lit.)
Vapor density 2.9 (vs air)
Vapor pressure 24.45 psi (55 °C)
Refractive index n20/D 1.424(lit.)
Flash point 39-40°℃
Storage conditions room temp
Solubility Miscible with ethyl acetate, ethanol, hexane, methanol, diethyl ether, n-octanol, acetone, benzene, carbon tetrachloride, diethyl ether, and chloroform.
Form liquid
Color APHA:≤10
Specific gravity 1.329 (20/20℃)
Odor Odor threshold 160 to 230 ppm
pH value 7 (20°C)
Olfactory threshold 160ppm
Explosion limit values 13-22%(V)
Water solubility 20 g/L (20 ºC)
Maximum wavelength(λmax) λ: 235 nm Amax: 1.00λ: 240 nm Amax: 0.20λ: 250 nm Amax: 0.05λ: 260 nm Amax: 0.02λ: 340-400 nm Amax: 0.01
Merck 146,063
BRN 1730800
Henry’s Law Constant 2.49 at 30 °C (headspace-GC, Sanz et al., 1997)
Dielectric constant 9.1(20℃)
Exposure limits TLV-TWA 50 ppm (~175 mg/m3) (ACGIH);
carcinogenicity: Suspected Human Carcinogen (ACGIH), Animal Sufficient Evidence,
Human Inadequate Evidence (IARC).
Stability Volatile
LogP 1.25
Surface tension 26.5mN/m at 20°℃
CAS database 75-09-2(CAS DataBase Reference)
NIST chemical information Methylene chloride(75-09-2)
(IARC) Carcinogen classification 2A (Vol. Sup 7,71, 110) 2017
EPA chemical information Methylene chloride (75-09-2)
Absorption in accordance

 

Certificate of Analysis
Commodity Dichloromethane(MC) Samping date 20250910
Batch number 3703W7118180 Inspection date 20250910
Analytical Items Index Result
Superior First-grade Qualified
appearance Colorless clarify, without suspended solids, no mechanical magazine Qualified
Chromaticity(in Hazen)
(Po-Co),≤
10 10
Acidity(HCL),%≤ 0.0004 0.0008
Moisture,% ≤ 0.01 0.02 0.03 0.0056
Dichloromethane,%≥ 99.9 99.5 99.2 99.98
Evaporation residue,%≤ 0.0005 0.001 /
Conclusion super grade
Note
Applications

The primary application of dichloromethane is as a solvent. Dichloromethane possesses strong solvent properties, a low boiling point, and relatively low toxicity and reactivity, making it the most frequently used organic solvent in organic synthesis. Its role as a solvent is nearly equivalent to that of water in inorganic salt chemistry.

It is extensively used in the production of safety film, polycarbonate, and as a solvent for coatings, metal degreaser, aerosol propellant, polyurethane foam agent, release agent, and paint remover. In the pharmaceutical industry, it serves as a reaction medium for the preparation of ampicillin, amoxicillin, and cephalosporin, among others; it is also used as a solvent in film production, a petroleum dewaxing solvent, an aerosol propellant, an organic synthesis extractant, a foaming agent for polyurethane and other foam plastics, and a metal cleaner.

Film production accounts for 50% of total consumption, pharmaceuticals account for 20%, cleaning agents and the chemical industry account for 20%, and other applications account for 10%.

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