Methyl Formate CAS 107-31-3
Methyl Formate CAS 107-31-3
  • CAS:107-31-3
    MDL:MFCD00003291
    EINECS:203-481-7
    RTECS:LQ8925000
    BRN:1734623
    PubChem:24857508
    Molecular Formula:C2H4O2

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Base

Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. It has the chemical formula HCOOCH3. The simplest example of a carboxylate ester, it is a colourless liquid with an ethereal odour, high vapor pressure, and low surface tension. It is a precursor to many other compounds of commercial interest.

Properties
Formula C2H4O2 / HCOOCH3
Molecular mass 60.1
Boiling point:
Melting point -100°C
Relative density (water = 1) 0.97
Solubility in water, g/100ml at 20°C 30 (good)
Vapour pressure, kPa at 20°C 64
Relative vapour density (air = 1) 2.1
Relative density of the vapour/air-mixture at 20°C (air = 1) 1.7
Flash point -19°C
Auto-ignition temperature 449°C
Explosive limits, vol% in air 5-23
Octanol/water partition coefficient as log Pow -0.21
Applications

Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. These compounds are precursors or building blocks for many useful derivatives.

Because of its high vapor pressure, it is used for quick-drying finishes and as a blowing agent for some polyurethane foam applications. and as a replacement for CFCs, HCFCs, and HFCs. Methyl formate has near zero ozone depletion potential and zero global warming potential and a short atmospheric life of 3 days.

It is also used as an insecticide.